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Solar-driven tandem photoredox nickel-catalysed cross-coupling using modified carbon nitride
Chemical Science ( IF 7.6 ) Pub Date : 2020-06-25 , DOI: 10.1039/d0sc02131h
Yangzhong Qin 1 , Benjamin C M Martindale 1 , Rui Sun 1 , Adam J Rieth 1 , Daniel G Nocera 1
Affiliation  

Nickel-catalysed aryl amination and etherification are driven with sunlight using a surface-modified carbon nitride to extend the absorption of the photocatalyst into a wide range of the visible region. In contrast to traditional homogeneous photochemical methodologies, the lower cost and higher recyclability of the metal-free photocatalyst, along with the use of readily available sunlight, provides an efficient and sustainable approach to promote nickel-catalysed cross-couplings.

中文翻译:


使用改性氮化碳的太阳能驱动串联光氧化还原镍催化交叉耦合



使用表面改性的氮化碳在阳光下驱动镍催化的芳基胺化和醚化,将光催化剂的吸收扩展到广泛的可见光区域。与传统的均相光化学方法相比,无金属光催化剂的成本更低、可回收性更高,再加上容易获得的阳光的使用,提供了一种有效且可持续的方法来促进镍催化交叉偶联。
更新日期:2020-07-22
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