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An Alternative Approach to the Hydrated Imidazoline Ring Expansion (HIRE) of Diarene‐Fused [1.4]Oxazepines
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-06-25 , DOI: 10.1002/ejoc.202000789
Sergey Grintsevich 1 , Alexander Sapegin 1 , Elena Reutskaya 1 , Stefan Peintner 2 , Máté Erdélyi 2 , Mikhail Krasavin 1
Affiliation  

A new approach to the synthesis of 10‐ and 11‐membered lactams via hydrated imidazoline ring expansion is described. In addition to the ring expansion an alternative course of the hydrated imidazoline evolution was discovered, for the first time, which gave N‐aminoethyl derivatives.
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中文翻译:

丁二烯[1.4]奥氮平的水合咪唑啉环扩展(HIRE)的替代方法

描述了一种通过水合咪唑啉扩环合成10元和11元内酰胺的新方法。除了扩环以外,还首次发现了水合咪唑啉演化的替代过程,该过程产生了N-氨基乙基衍生物。
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更新日期:2020-06-25
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