Materials Science and Engineering: B ( IF 3.9 ) Pub Date : 2020-06-25 , DOI: 10.1016/j.mseb.2020.114606 Xiangfeng Chu , Zhengqiang Gan , Linshan Bai , Yongping Dong , Marina N. Rumyantseva
In this paper, BaSnO3 microtubes were prepared via electrospinning method using Ba(NO3)2 and SnCl4·5H2O as raw materials. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS), respectively; the gas sensing properties of the as-prepared sample were also investigated. The results revealed that BaSnO3 microtubes could be obtained by calcining the precursor at 700 °C for 6 h. It was revealed that the sensor device based on BaSnO3 microtubes (700 °C, 6 h) exhibited excellent selectivity and high response toward acetic acid vapor at the operating temperature of 245 °C, the ratio of S1000 ppm acetic acid to S1000 ppm ethanol was about 14.4; especially, when the concentration of acetic acid was as low as 0.3 ppm, the response was still able to reach 1.4.
中文翻译:
电纺丝法制备BaSnO 3微管的乙酸蒸气感测特性
本文以Ba(NO 3)2和SnCl 4 ·5H 2 O为原料,通过电纺法制备了BaSnO 3微管。所制备的样品分别通过X射线衍射(XRD),扫描电子显微镜(SEM)和X射线光电子能谱(XPS)进行表征。还研究了所制备样品的气敏特性。结果表明,将前体在700°C下煅烧6 h可制得BaSnO 3微管。据透露,基于BaSnO 3的传感器设备微管(700°C,6 h)在245°C的工作温度下表现出优异的选择性和对乙酸蒸气的高响应,S 1000 ppm乙酸与S 1000 ppm乙醇的比例约为14.4;特别是当乙酸的浓度低至0.3 ppm时,响应仍能达到1.4。