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Synthesis and Structure of the Copper(II) Chloride Complex with (2-Bromophenyl)thioacetic Acid Morpholide
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-25 , DOI: 10.1134/s1070363220050163
M. L. Petrov , E. A. Popova , M. N. Krivchun , A. V. Belyakov

Abstract

The cyclization of (2-bromophenyl)thioacetic acid morpholide to 2-(morpholin-4-yl)-1-benzothiophene in the presence of copper(II) chloride has been found to involve intermediate formation of a complex consisting of two thioamide molecules and one copper cation. The complex has been isolated, and its molecular structure parameters have been determined by quantum chemical calculations.


中文翻译:

(2-溴苯基)硫代乙酸吗啉氯化铜(II)配合物的合成与结构

摘要

已经发现在氯化铜(II)存在下将(2-溴苯基)硫代乙酸吗啉化物环化为2-(吗啉-4-基)-1-苯并噻吩涉及中间形成由两个硫代酰胺分子和一种铜阳离子。该配合物已被分离,其分子结构参数已通过量子化学计算确定。
更新日期:2020-06-25
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