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Synthesis and Structure of the Copper(II) Chloride Complex with (2-Bromophenyl)thioacetic Acid Morpholide
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-25 , DOI: 10.1134/s1070363220050163 M. L. Petrov , E. A. Popova , M. N. Krivchun , A. V. Belyakov
中文翻译:
(2-溴苯基)硫代乙酸吗啉氯化铜(II)配合物的合成与结构
更新日期:2020-06-25
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-25 , DOI: 10.1134/s1070363220050163 M. L. Petrov , E. A. Popova , M. N. Krivchun , A. V. Belyakov
Abstract
The cyclization of (2-bromophenyl)thioacetic acid morpholide to 2-(morpholin-4-yl)-1-benzothiophene in the presence of copper(II) chloride has been found to involve intermediate formation of a complex consisting of two thioamide molecules and one copper cation. The complex has been isolated, and its molecular structure parameters have been determined by quantum chemical calculations.中文翻译:
(2-溴苯基)硫代乙酸吗啉氯化铜(II)配合物的合成与结构