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Some Features of the Reactions of 3-Nitro-6-phenylhexa-3,5-dien-2-one with Thiophenols
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-25 , DOI: 10.1134/s1070363220050011 R. I. Baichurin , V. D. Sergeev , N. I. Aboskalova , L. V. Baichurina , S. V. Makarenko
中文翻译:
3-硝基-6-苯基六-3,5-二烯-2-酮与硫酚反应的一些特征
更新日期:2020-06-25
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-25 , DOI: 10.1134/s1070363220050011 R. I. Baichurin , V. D. Sergeev , N. I. Aboskalova , L. V. Baichurina , S. V. Makarenko
Abstract
The reaction of 3-nitro-6-phenylhexa-3,5-diene-2-one with 4-methyl- and 4-chlorothiophenols yields 1,4- and 1,6-addition products at conjugated dienone system. By the example of the 1,4-addition adduct of 4-methylthiophenol, its conversion in solution to the 1,6-addition product was shown. 4-Methyl-3-nitro-2-styryl-2,3-dihydrobenzo[b][1,4]thiazepine was synthesized by reacting 3-nitro-6-phenylhexa-3,5-dien-2-one with o-aminothiophenol.中文翻译:
3-硝基-6-苯基六-3,5-二烯-2-酮与硫酚反应的一些特征