Abstract

The reaction of 3-nitro-6-phenylhexa-3,5-diene-2-one with 4-methyl- and 4-chlorothiophenols yields 1,4- and 1,6-addition products at conjugated dienone system. By the example of the 1,4-addition adduct of 4-methylthiophenol, its conversion in solution to the 1,6-addition product was shown. 4-Methyl-3-nitro-2-styryl-2,3-dihydrobenzo[b][1,4]thiazepine was synthesized by reacting 3-nitro-6-phenylhexa-3,5-dien-2-one with o-aminothiophenol.

中文翻译：

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3-硝基-6-苯基六-3,5-二烯-2-酮与硫酚反应的一些特征

摘要

3-硝基-6-苯基六-3,5-二烯-2-酮与4-甲基-和4-氯硫代苯酚的反应在共轭二烯酮体系下生成1,4-和1,6-加成产物。以4-甲基硫代苯酚的1，4-加成加合物为例，显示了其在溶液中转化为1，6-加成产物。4-3--3-硝基-2-苯乙烯-2-2，3-二氢苯并[ b ] [1,4]噻嗪类通过使3-硝基-6-苯基六-3,5-二-2-酮与邻-氨基苯硫酚。