A cubane-type manganese complex with H2O oxidation capabilities,Sustainable Energy & Fuels

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A cubane-type manganese complex with H2O oxidation capabilities
Sustainable Energy & Fuels ( IF 5.6 ) Pub Date : 2020-06-24 , DOI: 10.1039/d0se00701c
Swetanshu Tandon _{1,

2,

3,

4,

5} , Joaquín Soriano-López _{1,

2,

3,

4,

5} , Amal C. Kathalikkattil _{1,

2,

3,

4,

5} , Guanghua Jin _{1,

2,

3,

4,

5} , Paul Wix _{1,

2,

3,

4,

5} , Munuswamy Venkatesan _{2,

3,

4,

5,

6} , Ross Lundy _{1,

2,

3,

4,

5} , Michael A. Morris _{1,

2,

3,

4,

5} , Graeme W. Watson _{1,

2,

3,

4,

5} , Wolfgang Schmitt _{1,

2,

3,

4,

5}

Affiliation

We report the synthesis and characterisation of [Mn₈K₂O₄(OH)₂((CH₃)₃CCOO)₁₆(CH₃CN)₂] whose cluster core shares some features with the oxygen evolving complex (OEC), the natural water oxidation catalyst. Importantly, this complex provides a bio-inspired complex that promotes catalytic H₂O oxidation at neutral pH value.

中文翻译：

具有H2O氧化能力的古巴型锰配合物

我们报告了[Mn ₈ K ₂ O ₄（OH）₂（（CH ₃）₃ CCOO）₁₆（CH ₃ CN）₂ ]的合成和表征，其簇芯与析氧络合物（OEC）具有某些特征，天然水氧化催化剂。重要的是，这种络合物提供了一种生物启发性的络合物，可在中性pH值下促进催化H ₂ O氧化。

更新日期：2020-08-25

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