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Regioselective Synthesis of α-Phosphinoylnaphthols through Rhodium-Catalyzed Annulation of 1-Alkynylphosphine Oxides with Sulfoxonium Ylides
Synlett ( IF 1.7 ) Pub Date : 2020-06-23 , DOI: 10.1055/s-0040-1707892 Wucheng Xie 1 , Junjun Shi , Binting Lin , Xinyi Jian , Qinhong Lin
Synlett ( IF 1.7 ) Pub Date : 2020-06-23 , DOI: 10.1055/s-0040-1707892 Wucheng Xie 1 , Junjun Shi , Binting Lin , Xinyi Jian , Qinhong Lin
Affiliation
α-Phosphinoylnaphthols were obtained by redox-neutral annulation of 1-alkynylphosphine oxides with α-carbonyl sulfoxonium ylides under rhodium(III) catalysis. This protocol shows good regioselectivity and broad functional-group tolerance.
中文翻译：
通过铑催化环化 1-炔基氧化膦与锍叶立德的区域选择性合成 α-膦酰基萘酚
α-膦酰基萘酚是通过 1-炔基氧化膦与 α-羰基锍叶立德在铑 (III) 催化下氧化还原中性环化获得的。该协议显示出良好的区域选择性和广泛的功能组耐受性。
更新日期：2020-06-23
中文翻译：
通过铑催化环化 1-炔基氧化膦与锍叶立德的区域选择性合成 α-膦酰基萘酚
α-膦酰基萘酚是通过 1-炔基氧化膦与 α-羰基锍叶立德在铑 (III) 催化下氧化还原中性环化获得的。该协议显示出良好的区域选择性和广泛的功能组耐受性。
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