Recent advances in photoelectrochemical cells (PECs) for organic synthesis,Organic Chemistry Frontiers

当前位置： X-MOL 学术 › Org. Chem. Front. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Recent advances in photoelectrochemical cells (PECs) for organic synthesis
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-06-23 , DOI: 10.1039/d0qo00486c
Yan-Chen Wu _{1,

2,

3,

4} , Ren-Jie Song _{1,

2,

3,

4} , Jin-Heng Li _{1,

2,

3,

4,

5}

Affiliation

Photoelectrochemical cells (PECs) have emerged as an environmentally friendly tool for fuel production, conversion of carbon dioxide, water splitting, and pollutant degradation in the past few years. Although PECs show advantages in these areas, their application in organic synthesis has just begun. Recently, oxidation, C–H functionalization and cross-coupling have been successfully achieved in PECs by the use of an oxidizing photoanode, such as BiVO₄ or WO₃, for the construction of C–N, C–O and C–P bonds. This highlight article focuses on the application of PECs in organic synthesis reactions and their reaction mechanisms, with a special emphasis on enantioselective conversions.

中文翻译：

用于有机合成的光电化学电池（PEC）的最新进展

在过去的几年中，光电化学电池（PEC）已经成为一种用于燃料生产，二氧化碳转化，水分解和污染物降解的环保工具。尽管PEC在这些领域显示出优势，但它们在有机合成中的应用才刚刚开始。最近，通过使用氧化性光阳极（如BiVO ₄或WO _3）在PEC中成功实现了氧化，CH-H功能化和交叉偶联，以构建C-N，C-O和C-P键。本文重点介绍了PEC在有机合成反应及其反应机理中的应用，特别强调了对映选择性转化。

更新日期：2020-07-14

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11