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Solid Electrolyte Interfaces: The Effect of Interfacial Charge Distribution on Chemical Compatibility and Stability of the High Voltage Electrodes (LiCoPO4, LiNiPO4)/Solid Electrolyte (LiPON) Interface (Adv. Mater. Interfaces 12/2020)
Advanced Materials Interfaces ( IF 5.4 ) Pub Date : 2020-06-23 , DOI: 10.1002/admi.202070070
Gennady Cherkashinin 1 , Zhihang Yu 1 , Robert Eilhardt 1 , Lambert Alff 1 , Wolfram Jaegermann 1
Affiliation  

In article number 2000276, Gennady Cherkashinin and co‐workers describe an experimental approach to predict interfacial chemical reactions in battery systems. This new approach is of particular interest for the development of a new generation of all‐solid‐state 5 V Li ion batteries. The key parameters are the electrochemical and ionization potentials of the involved materials. Interface stability is achieved by pulling apart the ionization potentials of cathode and electrolyte as indicated by the two hands. The experimental investigation of the internal interface of a typical solid‐state battery is sketched on the right side. The suppression of detrimental interface reactions is an important step in the development of high energy density batteries for e‐mobility.
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中文翻译:

固体电解质接口:界面电荷分布对高压电极(LiCoPO4,LiNiPO4)/固体电解质(LiPON)接口的化学相容性和稳定性的影响(高级材料接口12/2020)

Gennady Cherkashinin及其同事在编号2000276中描述了一种预测电池系统中界面化学反应的实验方法。这种新方法对于开发新一代全固态5 V Li离子电池特别有用。关键参数是所涉及材料的电化学和电离势。如两只手所示,通过拉开阴极和电解质的电离电势可实现界面稳定性。右侧是对典型固态电池内部接口的实验研究。抑制有害界面反应是开发用于电动汽车的高能量密度电池的重要一步。
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更新日期:2020-06-23
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