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Effect of different copper sources on the morphology of cuprous oxide and its application as a non-enzymatic glucose sensor
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2020-06-23 , DOI: 10.1016/j.snb.2020.128485
Wenbin Liu , Guochun Chai , Xingming Zhao , Yuxiang Dai , Yang Qi

Herein, Cu2O with different morphology were successfully synthesized by simply adjusting the copper sources via a seed-medium process. Cu2O cubes with uniform size and stacked octahedrons (stacked by the self-assembly of cubic Cu2O) were obtained. The growth mechanism of cubes and stacked octahedrons were studied and applied to non-enzymatic glucose detection. The obtained electrode exhibited excellent capability toward the glucose oxidation. The S-Cu2O modified electrode showed the highest sensitivity of 2864 μA m·M−1 cm-2, the N-Cu2O modified electrode exhibited the widest linear range of 0.05–7.65 mM and the lowest LOD of 0.5 μM. Meanwhile all the samples showed fast response time. The S-Cu2O and N-Cu2O modified electrode also exhibited good selectivity and stability. Thanks to these obvious advantages, the modified electrodes have a promising prospect in practical applications.



中文翻译:

不同铜源对氧化亚铜形态的影响及其在非酶葡萄糖传感器中的应用

这里,铜2 ö用不同的形态通过简单地经由种子培养基过程调整所述铜源成功地合成。得到具有均匀尺寸的Cu 2 O立方体和堆积的八面体(通过立方Cu 2 O的自组装堆积)。研究了立方体和堆积八面体的生长机理,并将其应用于非酶法葡萄糖检测。所得电极显示出优异的葡萄糖氧化能力。S-Cu 2 O修饰电极的最高灵敏度为2864μAm·M -1  cm -2,N-Cu 2O修饰电极的线性范围最宽,为0.05–7.65 mM,最低LOD为0.5μM。同时,所有样品均显示出快速响应时间。S-Cu 2 O和N-Cu 2 O改性电极也表现出良好的选择性和稳定性。由于这些明显的优点,改性电极在实际应用中具有广阔的前景。

更新日期:2020-07-03
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