Crystalline porous materials including MOFs and COFs have generated great interest in energy storage fields especially batteries, because the ordered porous frameworks can offer a fast-ionic transportation and storage path without large volume variation. In recent years, pristine MOFs and COFs for battery application attract more interests. In this review paper, we highlight the recent progress of pristine MOFs and COFs in three main parts of battery, including electrode materials or host materials, solid-state electrolyte and separator. We summarize current challenges and advantages of the emerging field, make a deep understanding the mechanism behind and propose the design criteria for actual battery applications.

包括MOF和COF在内的结晶多孔材料在能量存储领域（尤其是电池）引起了极大的兴趣，因为有序的多孔框架可以提供快速的离子传输和存储路径，而体积变化不大。近年来，用于电池的原始MOF和COF引起了越来越多的兴趣。在这篇综述文章中，我们重点介绍了原始MOF和COF在电池三个主要部分的最新进展，包括电极材料或主体材料，固态电解质和隔膜。我们总结了新兴领域的当前挑战和优势，深入了解了背后的机制，并提出了实际电池应用的设计标准。