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Novel series of M La 2 WO 7 ( M = Sr, Ba) microwave dielectric ceramic systems with monoclinic structures
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-05-30 , DOI: 10.1007/s10854-020-03633-y
Xianjie Zhou , Huanfu Zhou , Qiang Wu , Xiaowen Luan , Sang Hu , Jiji Deng , Shixuan Li , Kuangguo Wang , Xiuli Chen

Novel series of MLa2WO7(M = Sr, Ba) ceramics were prepared via a traditional solid-state reaction method. The sintering characteristic, crystal structures, micromorphology and microwave dielectric performances of systems were systematically investigated. X-ray diffraction (XRD) and Rietveld refinement display that both SrLa2WO7(SLW) and BaLa2WO7(BLW) ceramics are monoclinic structure with Fdd (No. 14) space group. SLW and BLW ceramics have high relative density (more than 94%). The SLW ceramics sintered at 1400 °C exhibited good microwave dielectric performances with Ɛr = 23.2, Q × f = 29,720 GHz, τf = − 127 ppm/°C and the BLW ceramics sintered at 1300 °C had excellent properties of Ɛr = 25.3, Q × f = 36,473 GHz, τf = − 108 ppm/°C. These results show that MLa2WO7(M = Sr, Ba) ceramics could be candidates for microwave devices.



中文翻译:

具有单斜晶结构的M La 2 WO 7(M = Sr,Ba)微波介电陶瓷体系的新系列

 通过传统的固态反应方法制备了一系列新颖的M La 2 WO 7M = Sr,Ba)陶瓷。系统地研究了系统的烧结特性,晶体结构,微观形貌和微波介电性能。X射线衍射(XRD)和Rietveld精炼表明,SrLa 2 WO 7(SLW)和BaLa 2 WO 7(BLW)陶瓷均为具有Fdd(第14号)空间群的单斜晶结构。SLW和BLW陶瓷具有较高的相对密度(超过94%)。在1400℃下烧结的陶瓷SLW显示出良好的微波介电性能与ɛ ř= 23.2,Q  ×  ˚F = 29720千兆赫,τ ˚F = - 127 PPM /℃,并在1300℃下烧结的BLW陶瓷具有优异的性质ɛ - [R = 25.3,Q  ×  ˚F = 36473千兆赫,τ ˚F = - 108 ppm的/℃。这些结果表明,M La 2 WO 7M = Sr,Ba)陶瓷可能是微波设备的候选材料。

更新日期:2020-06-23
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