当前位置: X-MOL 学术Inorg. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Construction of Chiral "Triple-Decker" Nd(III) Nanocluster with High NIR Luminescence Sensitivity toward Co(II).
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-06-21 , DOI: 10.1021/acs.inorgchem.0c01146
Xia Liu 1 , Yanan Ma 1 , Xiaoping Yang 1 , Dongliang Shi 1 , Desmond Schipper 2 , Richard A Jones 2
Affiliation  

One Nd(III) complex [Nd3L3(OAc)3] (1) was synthesized from a conjugate Schiff base ligand H2L. It shows a chiral “triple-decker” structure (1.1 × 1.2 × 1.8 nm) with Nd(III) ions sandwiched between the Schiff base ligands. 1 exhibits NIR Nd(III) luminescence, and the LMET efficiency is calculated to be 13.8%. It displays high luminescence sensitivity and selectivity to Co(II). The KSV value and LOD of 1 to Co(II) are 9.96 × 104 M–1 and 0.97 μM, respectively.

中文翻译:

对Co(II)具有高NIR发光敏感性的手性“ Triple-Decker” Nd(III)纳米簇的构建。

一种Nd(III)配合物[Nd 3 L 3(OAc)3 ](1)是由共轭席夫碱配体H 2 L合成的。显示出手性“三层”结构(1.1×1.2×1.8 nm) Nd(III)离子夹在席夫碱配体之间。图1显示出NIR Nd(III)发光,并且LMET效率经计算为13.8%。它显示出高发光敏感性和对Co(II)的选择性。1到Co(II)的K SV值和LOD分别为9.96×10 4 M –1和0.97μM。
更新日期:2020-07-06
down
wechat
bug