Selective Carbon-Carbon Bond Cleavage of Cyclopropylamine Derivatives.,Chemical Reviews

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Selective Carbon-Carbon Bond Cleavage of Cyclopropylamine Derivatives.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-06-22 , DOI: 10.1021/acs.chemrev.0c00166
Olga O Sokolova ₁ , John F Bower _{1,

2}

Affiliation

This review summarizes synthetic developments reported from 1987 to 2019 that exploit C–C single bond cleavage of cyclopropylamine-based systems. The synthetic and mechanistic aspects of key methodologies are highlighted, and examples where aminocyclopropanes are exploited as key intermediates in multistep synthesis are also discussed. The review encompasses cases where aminocyclopropanes participate in polar reactions, pericyclic processes, radical-based reactions, and C–C bond activations.

中文翻译：

环丙胺衍生物的选择性碳-碳键裂解。

这篇综述总结了1987年至2019年间报道的利用环丙胺基体系的CC单键裂解的合成研究进展。重点介绍了关键方法的合成和机理方面，并讨论了将氨基环丙烷用作多步合成关键中间体的实例。该综述涵盖了氨基环丙烷参与极性反应，周环过程，基于自由基的反应和C–C键活化的情况。

更新日期：2020-06-22

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