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New crystal structures of alkali metal tetrakis(pentafluorophenyl)borates
Main Group Metal Chemistry ( IF 1.8 ) Pub Date : 2020-06-21 , DOI: 10.1515/mgmc-2020-0011
Daniel Duvinage 1 , Artem Schröder 1 , Enno Lork 1 , Jens Beckmann 1
Affiliation  

Abstract The crystal structures of the salts [Li(1,2-F2C6H4)] [B(C6F5)4] (1) and Cs[B(C6F5)4] (2) comprise six Li···F contacts (1.965(3) − 2.312(3) Å) and twelve Cs···F contacts (3.0312(1) − 3.7397(2) Å), respectively, which are significantly shorter than the sum of van der Waals radii (3.29 and 4.90 Å).

中文翻译:

碱金属四(五氟苯基)硼酸盐的新晶体结构

摘要 盐类 [Li(1,2-F2C6H4)] [B(C6F5)4] (1) 和 Cs[B(C6F5)4] (2) 的晶体结构包含六个 Li…F 触点 (1.965( 3) − 2.312(3) Å) 和十二个 Cs…F 触点 (3.0312(1) − 3.7397(2) Å),分别显着短于范德华半径之和(3.29 和 4.90 Å) .
更新日期:2020-06-21
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