Metal‐Organic Framework‐Based Catalysts for Oxidative Desulfurization,ChemCatChem

当前位置： X-MOL 学术 › ChemCatChem › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Metal‐Organic Framework‐Based Catalysts for Oxidative Desulfurization
ChemCatChem ( IF 3.8 ) Pub Date : 2020-06-22 , DOI: 10.1002/cctc.202000688
C. G. Piscopo ₁ , C. M. Granadeiro ₂ , S. S. Balula ₂ , D. Bošković ₁

Affiliation

Oxidative desulfurization (ODS) is emerging as the most promising methodology to remove refractive naturally occurring sulfides from fossil fuels. Metal‐organic frameworks (MOFs), a fascinating class of materials, are suitable as catalysts for this process due to the theoretical infinite number of combinations of polynuclear metal clusters and organic linkers. A rational fine‐tuning of the material structure, porosity and chemical functionality have given rise to a considerable number of MOF‐based catalytic active materials. Furthermore, MOFs can act as host, with programmable cavity sizes to accommodate catalytic species, forming novel robust catalytic MOF composite materials. Herein an account of this growing field of heterogeneous catalysis is reported and discussed, aiming to point out future outlooks and perspectives.

中文翻译：

基于金属-有机骨架的氧化脱硫催化剂

氧化脱硫（ODS）逐渐成为从化石燃料中去除自然产生的折射硫化物的最有前途的方法。金属有机骨架（MOF）是一类引人入胜的材料，由于理论上无数种多核金属簇和有机连接基的组合，因此适合作为该过程的催化剂。对材料结构，孔隙率和化学功能性的合理微调已经产生了大量基于MOF的催化活性材料。此外，MOF可以充当主体，具有可编程的腔体尺寸以容纳催化物质，从而形成新型的坚固的催化MOF复合材料。在此报道并讨论了这种不断增长的非均相催化领域，旨在指出未来的前景和观点。

更新日期：2020-06-22

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11