Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-06-20 , DOI: 10.1016/j.jphotochem.2020.112719 Li Wang , Ying-Qi Pan , Ji-Fa Wang , Yang Zhang , Yu-Jie Ding
A half-salamo-based fluorescent chemosensor HL based on 3,5-dichlorosalicylaldehyde was developed. Sensor HL showed a single selectivity for heavy metal Pb2+ ion by "on-turn" fluorescence in various common metal ions. After forming a 2 : 1 type complex with Pb2+ ion, the minimum detection limit (LOD) of HL for Pb2+ ion was calculated as 5.65 × 10−8 M. In addition, the complex formed by HL and Pb2+ ion was used as a new chemosensor L-Pb2+ for further recognition of cysteine (Cys), thereby releasing HL. The minimum detection limit (LOD) of Cys for L-Pb2+ was calculated as 3.80 × 10−7 M. The “on-off-on” mode of chemosensors HL and L-Pb2+ achieved by alternately adding Pb2+ and Cys has reached the recycling of chemosensors.
中文翻译:
一种高度选择性和灵敏的半萨拉莫荧光化学传感器,用于顺序检测Pb(II)离子和Cys
开发了基于3,5-二氯水杨醛的基于半萨拉莫的荧光化学传感器HL。传感器HL通过各种常见金属离子中的“开启”荧光显示出对重金属Pb 2+离子的单一选择性。与Pb 2+离子形成2:1型络合物后,HL对Pb 2+离子的最小检测限(LOD)计算为5.65×10 -8M。此外,由HL和Pb 2+形成的络合物离子被用作新的化学传感器L-Pb 2+以进一步识别半胱氨酸(Cys),从而释放HL。计算得出的L-Pb 2+的Cys最小检出限(LOD)为3.80×10 -7M。化学传感器HL和L-Pb 2+的“开-关-开”模式是通过交替添加Pb 2+而实现的Cys已达到化学传感器的回收利用。