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Tetravalent Platinum Complexes: Synthesis, Structure, and Antimicrobial Activity
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-06-20 , DOI: 10.1134/s1070363220040155
A. R. Tkacheva , V. V. Sharutin , O. K. Sharutina , N. M. Shlepotina , О. L. Kolesnikov , Yu. S. Shishkova , М. V. Peshikova

Abstract

The complexes [(C2H5)2NH2]2[PtCl6], [(C2H5)4N]2[PtCl6], and [(CH3)3NH]2[PtCl6] were prepared by the reaction of hexachloroplatinic acid with organylammonium chlorides in acetonitrile. Structure of these compounds was determined by X-ray analysis and infrared spectroscopy. The synthesized crystals consist of tetrahedral organylammonium cations and hexachloroplatinate octahedral anions. The antimicrobial activity of the synthesized complexes against the Escherichia coli strain M-17 was studied.


中文翻译:

四价铂络合物:合成,结构和抗菌活性

摘要

配合物为[(C 2 H 52 NH 2 ] 2 [PtCl 6 ],[(C 2 H 54 N] 2 [PtCl 6 ]和[(CH 33 NH] 2 [PtCl 6 ]。六氯铂酸与有机氯化铵在乙腈中反应制得。这些化合物的结构通过X射线分析和红外光谱确定。合成的晶体由四面体有机铵阳离子和六氯铂酸八面体阴离子组成。合成的复合物的抗微生物活性对大肠杆菌M-17菌株进行了研究。
更新日期:2020-06-20
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