Abstract

The complexes [(C₂H₅)₂NH₂]₂[PtCl₆], [(C₂H₅)₄N]₂[PtCl₆], and [(CH₃)₃NH]₂[PtCl₆] were prepared by the reaction of hexachloroplatinic acid with organylammonium chlorides in acetonitrile. Structure of these compounds was determined by X-ray analysis and infrared spectroscopy. The synthesized crystals consist of tetrahedral organylammonium cations and hexachloroplatinate octahedral anions. The antimicrobial activity of the synthesized complexes against the Escherichia coli strain M-17 was studied.

中文翻译：

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四价铂络合物：合成，结构和抗菌活性

摘要

配合物为[（C ₂ H ₅）₂ NH ₂ ] ₂ [PtCl ₆ ]，[（C ₂ H ₅）₄ N] ₂ [PtCl ₆ ]和[（CH ₃）₃ NH] ₂ [PtCl ₆ ]。六氯铂酸与有机氯化铵在乙腈中反应制得。这些化合物的结构通过X射线分析和红外光谱确定。合成的晶体由四面体有机铵阳离子和六氯铂酸八面体阴离子组成。合成的复合物的抗微生物活性对大肠杆菌M-17菌株进行了研究。