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Hybrid Composites of Quantum Dots, Monolayer WSe2, and Ag Nanodisks for White Light-Emitting Diodes
ACS Applied Nano Materials ( IF 5.3 ) Pub Date : 2020-06-17 , DOI: 10.1021/acsanm.0c01227
Chiao-Yun Chang, Cheng-Li Yu, Chen-An Lin, Hsiang-Ting Lin, Andrew Boyi Lee, Zheng-Zhe Chen, Li-Syuan Lu, Wen-Hao Chang, Hao-Chung Kuo, Min-Hsiung Shih

We investigated hybrid zero-dimensional core–shell CdSe/ZnS quantum dot (QD)/two-dimensional monolayer WSe2 semiconductors with an Ag nanodisk (ND) for manipulating plasmonic-enhanced photoluminescence (PL) and color conversion efficiency. The absorption spectrum of the local surface plasmon resonance (LSPR) effectively overlaps with that of QDs or monolayer WSe2 to considerably enhance PL. The broad absorption spectrum of the LSPR simultaneously overlapped with the emission spectrum of QDs and the absorption spectrum of excitons in WSe2 to enhance the color conversion efficiency. The highest efficiency of color conversion from QDs to WSe2 with Ag ND was 53%. In the future, hybrid QD/transition metal dichalcogenide light emitters could be further integrated with GaN-based white light-emitting diodes to manipulate the color temperature and expand the color gamut to develop a miniature white light-emitting diode.

中文翻译:

量子点,单层WSe 2和Ag纳米盘用于白光发光二极管的混合复合材料

我们研究了具有Ag纳米盘(ND)的混合零维核壳CdSe / ZnS量子点(QD)/二维单层WSe 2半导体,以控制等离激元增强的光致发光(PL)和颜色转换效率。局部表面等离子体激元共振(LSPR)的吸收光谱与QD或单层WSe 2的吸收光谱有效重叠,从而显着增强了PL。LSPR的宽吸收光谱同时与QDs的发射光谱和WSe 2中激子的吸收光谱重叠,从而提高了颜色转换效率。从QD到WSe 2的色彩转换效率最高Ag ND为53%。将来,混合式QD /过渡金属二卤化二亚锡发光体可进一步与GaN基白色发光二极管集成在一起,以控​​制色温并扩展色域,从而开发出微型白色发光二极管。
更新日期:2020-07-24
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