Total Synthesis of Alstofolinine A,Asian Journal of Organic Chemistry

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Total Synthesis of Alstofolinine A
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-06-18 , DOI: 10.1002/ajoc.202000267
Sridhara Shanmukha Rao B. _{1,

2} , Amit Kumar _{1,

2} , Gangarajula Sudhakar _{1,

2}

Affiliation

The total synthesis of alstofolinine A (1 ) is accomplished from an easily accessible tetracyclic core 11 via 12 . Core 11 bears all the required stereocenters along with suitable functional groups for necessary transformations facilitated in quick accessing of the target molecule 1 in minimal steps. Besides, this synthesis further supports the absolute configuration of alstofolinine A (1 ).

中文翻译：

全合成Alofofolinine A

alstofolinine A（1）的总合成是通过一个容易获得的四环核11 经由 12完成的。核心11带有所有必需的立体中心以及合适的官能团，用于以最小的步骤快速访问目标分子1的必要转化。此外，该合成进一步支持了阿尔索福林碱A（1）的绝对构型。

更新日期：2020-08-08

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