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The New “Noble Gas” Molecule: A Molecular Trip beyond Atoms
Chem ( IF 19.1 ) Pub Date : 2020-06-18 , DOI: 10.1016/j.chempr.2020.06.009
Juan Casado , Nazario Martín

In a recent issue of Nature Chemistry, Jishan Wu and co-workers reported the hexacation species of a 3D conjugated molecular cage whose 50 π-electrons follow Hirsch’s rule of 3D aromaticity. We show how Hirsch’s rule connects hydrogenoid atoms, the (unprepared) decacation of the C60 fullerene, and the Wu group’s hexacation.



中文翻译:

新的“稀有气体”分子:超越原子的分子之旅

在最近一期的《自然化学》中,吴继山及其同事报道了一个3D共轭分子笼的六价阳离子物种,该笼中的50个π电子遵循Hirsch的3D芳香性法则。我们展示了赫希法则是如何连接氢原子,C 60富勒烯的(未准备好的)癸基化和Wu基的六阳离子化的。

更新日期:2020-06-18
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