High-performance, air-stable, n-type thermoelectric films from a water-dispersed nickel-ethenetetrathiolate complex and ethylene glycol,Journal of Materials Chemistry A

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High-performance, air-stable, n-type thermoelectric films from a water-dispersed nickel-ethenetetrathiolate complex and ethylene glycol
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2020-06-17 , DOI: 10.1039/d0ta04524a
Kazuki Ueda _{1,

2,

3,

4} , Yuto Yamada _{1,

2,

3,

4} , Toshiki Terao _{1,

2,

3,

4} , Kei Manabe _{1,

2,

3,

4} , Tomoyasu Hirai _{2,

3,

4,

5,

6} , Yuta Asaumi _{1,

2,

3,

4} , Syuji Fujii _{2,

3,

4,

5,

6} , Shintaro Kawano _{4,

7,

8} , Masahiro Muraoka _{2,

3,

4,

5,

6} , Michihisa Murata _{2,

3,

4,

5,

6}

Affiliation

An efficient solution-based process for the fabrication of air-stable n-type thermoelectric films is reported. A nickel-ethenetetrathiolate complex was synthesized in dimethyl formamide and used to produce a dispersion in an aqueous medium. The film, fabricated via a simple drop-casting method with ethylene glycol, exhibited a remarkably high thermoelectric n-type power factor of 33 μW m⁻¹ K⁻².

中文翻译：

由水分散的镍-四硫乙烯络合物和乙二醇制成的高性能，空气稳定的n型热电薄膜

报道了一种用于制造空气稳定的n型热电薄膜的基于解决方案的有效方法。在二甲基甲酰胺中合成了镍-乙撑四硫醇盐络合物，并用于在水性介质中制得分散液。通过简单的滴铸法用乙二醇制备的膜表现出非常高的33μWm ^-1 K ^-2的热电n型功率因数。

更新日期：2020-06-30

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