A porous metal–organic framework [Ba(H₂L^{LOMe 2−} )·DMF·H₂O]·2DMF (UPC‐2 ) (H₄L^LOMe = 4ʹ,4ʹʹʹ‐(2,3,6,7‐tetramethoxyanthracene‐9,10‐diyl)bis([1,1ʹ‐biphenyl]‐3,5‐dicarbo‐xylic acid N,N‐Dimethylformamide [DMF]), which can act as an excellent chemiluminescence microreactor, is designed and constructed. In the framework of UPC‐2 , the catalytic Ba cluster and electron‐rich anthracene fluorescent centers are fixed and interconnected in an orderly fashion, and this can shorten the energy transfer path and weaken the relaxation of the chemiluminescence process. Meanwhile, the rhombic channels of UPC‐2 can provide a proper diffusion ratio of reactants to support a stable and continuous energy supply. The UPC‐2 chemiluminescence microreactor exhibits an ultrastrong and long‐lasting light emission, which possesses potential application in emergency lights and biological mapping. The concept of the chemiluminescence microreactor and its construction using a metal–organic framework as a platform will promote further research in the design and fabrication of functional MOFs for chemiluminescence applications.

中文翻译：

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用于超强且持久发光的集成化学发光微反应器。

多孔金属有机骨架[Ba(H ₂ L ^{LOMe 2−} )·DMF·H ₂ O]·2DMF ( UPC-2 ) (H ₄ L ^LOMe = 4ʹ,4ʹʹʹ‐(2,3,6,7‐四甲氧基蒽)设计并构建了-9,10-二基）双（[1,1ʹ-联苯]-3,5-二羧酸N,N-二甲基甲酰胺[DMF]），它可以作为一种优异的化学发光微反应器。在UPC-2的框架中，催化Ba团簇和富电子蒽荧光中心有序地固定和互连，这可以缩短能量传递路径并减弱化学发光过程的弛豫。UPC-2可以提供适当的反应物扩散比，支持稳定、持续的能量供应，UPC-2化学发光微反应器表现出超强、持久的发光特性，在应急灯和生物测绘方面具有潜在的应用前景。化学发光微反应器及其以金属有机框架为平台的构建将促进化学发光应用功能性MOF的设计和制造的进一步研究。