Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-06-17 , DOI: 10.1016/j.cplett.2020.137724 Sajad Ahmad Bhat , Nusrat Rashid , Mudasir Ahmad Rather , Sarwar Ahmad Bhat , Pravin P. Ingole , Mohsin Ahmad Bhat
Herein, we report highly catalytic reductive degradation of xanthene based dye, Rhodamine B (RhB) over Palladium-reduced graphene oxide (Pd-rGO) nanocomposites. In presence of minimum catalytic amount (viz. 0.025 mg of Pd-rGO) employed for the reduction of RhB, the reduction completes in less than 30 s with an apparent rate constant (kapp) of 63.83 × 10−3 s−1 and highest ever to be reported catalytic factor/normalized rate constant (knor) of 2.6 × 10−3 s−1g−1. The results were compared with catalytic performance of Silver-reduced graphene oxide (Ag-rGO) and the kapp was observed to follow the order: kPd-rGO ≫ kAg-rGO > kUncat.
中文翻译:
钯还原氧化石墨烯纳米复合材料对罗丹明B的高效催化还原降解
在本文中,我们报道了在钯还原的氧化石墨烯(Pd-rGO)纳米复合材料上,基于氧杂蒽的染料若丹明B(RhB)的高度催化还原性降解。在用于还原RhB的最小催化量(即0.025 mg Pd-rGO)存在下,还原在不到30 s的时间内完成,表观速率常数(k app)为63.83×10 -3 s -1和有史以来最高的催化因子/归一化速率常数(k nor)为2.6×10 -3 s -1 g -1。将结果与还原银氧化石墨烯(Ag-rGO)和k app的催化性能进行了比较观察到按照顺序:ķ的Pd-RGO » ķ的Ag-RGO > ķ Uncat。