Anodic oxidation with electrogenerated H₂O₂ (AO-H₂O₂) was applied to treat 130 mL of antihypertensive drug captopril in sulfate medium, urban wastewater and synthetic urine using a BDD, Pt or IrO₂ anode and an air-diffusion cathode. Oxidants were OH formed during O₂ evolution and active chlorine formed via anodic oxidation of Cl⁻. Drug removal decreased as: BDD > Pt > IrO₂. The effect of pH and current density was examined. Further, 2.5 L of drug solutions in the same matrices with Fe²⁺ at pH 3.0 were treated by solar photoelectro-Fenton (SPEF) using a solar pre-pilot flow plant with a Pt/air-diffusion cell and a planar photoreactor. In sulfate medium, SPEF outperformed AO-H₂O₂ and electro-Fenton because of the efficient Fe³⁺ photoreduction. Low mineralization was achieved by the small generation of photoactive Fe(III)-carboxylate complexes. In urban wastewater, captopril was more rapidly removed due to active chlorine. Two heterocyclic derivatives and four aliphatic acids were detected.

使用BDD，Pt或IrO ₂阳极和空气扩散阴极，使用电生H ₂ O ₂（AO-H ₂ O ₂）进行阳极氧化，以处理130 mL硫酸盐介质，城市废水和合成尿中的降压药卡托普利。。氧化剂被期间öOH形成₂演化和地通过Cl的阳极氧化形成的活性氯^- 。药物去除降低为：BDD> Pt> IrO ₂。检查了pH和电流密度的影响。此外，在相同基质中将2.5 L含Fe ²⁺的药物溶液使用带有Pt /空气扩散池和平面光反应器的太阳能预试流动装置，通过太阳能光电Fenton（SPEF）处理pH为3.0的溶液。在硫酸盐介质中，由于有效的Fe ^3+光还原作用，SPEF的性能优于AO-H ₂ O ₂和电子Fenton 。通过少量光敏性Fe（III）-羧酸盐络合物的生成可以实现低矿化作用。在城市废水中，由于活性氯的存在，卡托普利的去除速度更快。检测到两个杂环衍生物和四个脂肪酸。