Abstract

It is shown that the molecular composition of the vapor–gas phase of many chemical compounds and their mixtures, including carbides, nitrides, and oxides, is substantially more complex and diverse than it appeared before. In addition to monomeric molecules, various gaseous molecules of these compounds are detected in the vapors of carbides, nitrides, and oxides. Data on the composition of the vapors of nitrides of almost all the chemical elements from the periodic system as well as thermodynamic properties of gaseous nitrides are presented in this work.

中文翻译：

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化学元素的氮化物蒸发过程的热力学

摘要

结果表明，许多化合物及其混合物（包括碳化物，氮化物和氧化物）的气相气相分子组成比以前出现的复杂得多。除单体分子外，还在碳化物，氮化物和氧化物的蒸气中检测到这些化合物的各种气态分子。这项工作提供了有关来自周期系统的几乎所有化学元素的氮化物蒸气组成以及气态氮化物的热力学性质的数据。