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Oxidative cascade cyclization of 2-cyano-3-arylaniline derived acrylamides with toluenes, ethers, aliphatic alcohols or simple alkanes
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-06-16 , DOI: 10.1039/d0qo00535e
Wen-Jin Xia 1, 2, 3, 4 , Yangchun Xin 5, 6, 7, 8 , Zhi-Wei Zhao 1, 2, 3, 4 , Xin Chen 1, 2, 3, 4 , Xiang-Xiang Wang 1, 2, 3, 4 , Yi Li 1, 2, 3, 4 , Guanlin Wang 1, 2, 3, 4 , Ya-Min Li 1, 2, 3, 4
Affiliation  

An oxidative radical cascade cyclization of 2-cyano-3-arylaniline derived acrylamides with hydrocarbons is described. The present reaction exhibits a wide substrate scope, and toluenes, ethers, aliphatic alcohols and simple alkanes can be employed as coupling partners, providing access to alkyl substituted pyrido[4,3,2-gh]phenanthridines.

中文翻译:

2-氰基-3-芳基苯胺衍生的丙烯酰胺与甲苯,醚,脂族醇或简单烷烃的氧化级联环化

描述了2-氰基-3-芳基苯胺衍生的丙烯酰胺与烃的氧化自由基级联环化。本反应显示出较宽的底物范围,并且甲苯,醚,脂族醇和简单的烷烃可以用作偶联伴侣,从而提供了烷基取代的吡啶并[4,3,2- gh ]菲啶的入口。
更新日期:2020-07-28
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