Noble gas endohedral fullerenes,Chemical Science

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Noble gas endohedral fullerenes
Chemical Science ( IF 7.6 ) Pub Date : 2020-06-16 , DOI: 10.1039/d0sc02507k
Said Jalife ₁ , Jessica Arcudia ₁ , Sudip Pan ₂ , Gabriel Merino ₁

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This review focuses on the available experimental and theoretical investigations on noble gas (Ng) endohedral fullerenes, addressing essential questions related to the mutual effects that confinement of one or more Ng atoms induces on the electronic structure, bonding, and different properties of fullerenes. It also summarizes the different contributions to the mechanisms of formation and decomplexation, the reactivity towards Diels–Alder cycloaddition reactions, the chemical bonding situation of Ng endohedral fullerenes, and the interactions that dominate within these systems.

中文翻译：

稀有气体内嵌富勒烯

本综述重点介绍了惰性气体 (Ng) 内嵌富勒烯的现有实验和理论研究，解决了与一个或多个 Ng 原子的限制对富勒烯的电子结构、键合和不同性能产生的相互影响相关的基本问题。它还总结了对形成和解络机制的不同贡献、狄尔斯-阿尔德环加成反应的反应性、Ng内嵌富勒烯的化学键合情况以及这些系统中占主导地位的相互作用。

更新日期：2020-07-08

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