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Li 2 CoTi 3 O 8 and its composite nanofibers as high performance and long cycle lithium ion electrode materials
Journal of Nanoparticle Research ( IF 2.1 ) Pub Date : 2020-06-16 , DOI: 10.1007/s11051-020-04908-5
Yuzhou Liu , Shuiping Huang , Chao Wang , Nan Gao , Xiaoyang Qiu , Xing Li

In this work, Li2CoTi3O8 nanofibers and Li2CoTi3O8·CoTiO3·TiO2 (LCT) composite nanofibers as anode materials in lithium-ion batteries (LIBs) were successfully prepared by a traditional electrospinning technology, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and mappings. XRD confirms that the composite materials lattice planes well correspond to the patterns of Li2CoTi3O8, CoTiO3, and TiO2, respectively. SEM and TEM exhibits the fabricated composites are one-dimensional nanofibers with the diameter of 250~300 nm and 150~200 nm after annealing, respectively. The electrochemical properties of the materials for LIBs are investigated to indicate that the (LCT) composite nanofibers hold high reversible capacity of 201.68 mAh g−1 after 120 cycles and high rate capability at different current densities.

Li2CoTi3O8·CoTiO3·TiO2 (LCT) composite nanofibers were prepared through a electrospinning, which hold high reversible capacity of 201.68 mAh g−1 after 120 cycles and high rate capability at different current densities.



中文翻译:

Li 2 CoTi 3 O 8及其复合纳米纤维作为高性能长周期锂离子电极材料

通过传统的静电纺丝技术成功制备了Li 2 CoTi 3 O 8纳米纤维和Li 2 CoTi 3 O 8 ·CoTiO 3 ·TiO 2(LCT)复合纳米纤维作为锂离子电池(LIBs)的负极材料。通过X射线衍射(XRD),扫描电子显微镜(SEM),高分辨率透射电子显微镜(HRTEM),能量色散光谱仪(EDS),X射线光电子能谱(XPS),热重分析(TGA)进行表征和映射。XRD证实复合材料的晶格平面与Li 2 CoTi 3 O的图案非常吻合如图8所示,分别为CoTiO 3和TiO 2。扫描电镜和透射电镜显示,所制备的复合材料是一维纳米纤维,经退火后直径分别为250〜300 nm和150〜200 nm。研究了用于LIB的材料的电化学性质,以表明(LCT)复合纳米纤维在120次循环后具有201.68 mAh g -1的高可逆容量,并在不同电流密度下具有高倍率容量。

通过电纺丝法制备了Li 2 CoTi 3 O 8 ·CoTiO 3 ·TiO 2(LCT)复合纳米纤维,该复合纤维在120次循环后具有201.68 mAh g -1的高可逆容量,在不同电流密度下具有高倍率能力。

更新日期:2020-06-16
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