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Comparison of tritium release behavior in Li2TiO3 and promising core-shell Li2TiO3–Li4SiO4 biphasic ceramic pebbles
Journal of Nuclear Materials ( IF 2.8 ) Pub Date : 2020-06-15 , DOI: 10.1016/j.jnucmat.2020.152330
Qiang Qi , Jing Wang , Qilai Zhou , Yingchun Zhang , Mingzhong Zhao , Shouxi Gu , Moeko Nakata , Haishan Zhou , Yasuhisa Oya , Guang-Nan Luo

In a D-T fusion reactor, self-sufficiency of tritium is one of the critical issues to maintain steady-state operation of the reactor. Li2TiO3 and core-shell Li2TiO3–Li4SiO4 biphasic pebbles have been irradiated by thermal neutrons in Kyoto University. T-TDS (Tritium - Thermal Desorption Spectroscopy) was performed in Shizuoka University. There is one main tritium trapping site in neutron irradiated Li2TiO3. However, three tritium trapping sites are introduced in neutron irradiated core-shell Li2TiO3– Li4SiO4. The two peaks at lower temperature agree with that of Li2TiO3 which can be attributed to tritium release from Li2TiO3 including shell and core. The peak at higher temperature is mainly considered as tritium release from Li4SiO4. The amount of tritium released from core-shell Li2TiO3–Li4SiO4 is slight higher than that of Li2TiO3. The kinetic parameters of tritium diffusion in Li2TiO3 have been obtained. In the case of Li2TiO3 and core-shell Li2TiO3–Li4SiO4, almost all the tritium is released as HTO observed from T-TDS. Purge gas has little effect on tritium release, indicating tritium release from Li2TiO3 was mainly controlled by tritium diffusion in Li2TiO3 grain.



中文翻译:

Li 2 TiO 3和有希望的核壳型Li 2 TiO 3 –Li 4 SiO 4双相陶瓷卵石中release释放行为的比较

在DT聚变反应堆中,self的自给自足是维持反应堆稳态运行的关键问题之一。京都大学的热中子辐照了Li 2 TiO 3和核壳型Li 2 TiO 3 -Li 4 SiO 4双相小卵石。T-TDS(rit-热脱附光谱法)在静冈大学进行。在中子辐照的Li 2 TiO 3中有一个主要的tri捕获位点。然而,在中子辐照的核壳Li 2 TiO 3 -Li 4 SiO 4中引入了三个tri俘获位点。较低温度下的两个峰与Li 2 TiO 3的峰一致,这可以归因于tri从Li 2 TiO 3中释放出的including,包括壳和核。高温下的峰主要被认为是Li从Li 4 SiO 4中释放出来。从核壳型Li 2 TiO 3 -Li 4 SiO 4中释放出的than量略高于Li 2 TiO 3。获得了Li在Li 2 TiO 3中扩散的动力学参数。在Li 2 TiO 3的情况下和核-壳型Li 2 TiO 3 -Li 4 SiO 4,几乎所有all都以HTO的形式从T-TDS中释放出来。吹扫气体对tri的释放几乎没有影响,表明从Li 2 TiO 3释放tri主要受mainly在Li 2 TiO 3晶粒中的扩散控制。

更新日期:2020-07-02
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