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Ru-doped transition metal catalysts for liquid-phase Fischer–Tropsch synthesis
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.7 ) Pub Date : 2020-06-15 , DOI: 10.1007/s11144-020-01800-0
Mariia E. Markova , Alexandra V. Gavrilenko , Antonna A. Stepacheva , Valentina G. Matveeva , Mikhail G. Sulman , Viktor I. Panfilov , Esther M. Sulman

In this paper the catalytic activity of the Ru-doped polymer-based catalysts synthesized by the hydrothermal deposition is described. The catalytic properties of the synthesized systems were studied in the liquid-phase Fischer–Tropsch synthesis for the production of liquid gasoline and diesel-range hydrocarbons. The catalysts showed high CO hydrogenating activity allowing more than 20% of CO conversion to be obtained for one cycle. The yield of liquid hydrocarbons (mainly linear C5-C13) was found to be more than 80%. The addition of the ruthenium to the commonly used Co, Ni, and Fe enhances both the catalytic activity and the yield of the liquid hydrocarbons. The catalysts seem to be stable for minimum 80 h on stream.



中文翻译:

钌掺杂的过渡金属费托合成催化剂

本文描述了通过水热沉积合成的Ru掺杂的聚合物基催化剂的催化活性。在液相费-托合成法中研究了合成系统的催化性能,用于生产液态汽油和柴油范围的碳氢化合物。催化剂显示出高的CO加氢活性,允许在一个循环中获得20%以上的CO转化率。发现液态烃(主要是线性C 5 -C 13)的产率大于80%。将钌添加到常用的Co,Ni和Fe中既可以提高催化活性,又可以提高液态烃的收率。催化剂在运行至少80小时后似乎稳定。

更新日期:2020-06-15
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