当前位置: X-MOL 学术Dokl. Earth Sci. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Isotope Fractionation and the Pressure Effect on 18O/16O in Kyanite-Sillimanite-Andalusite Polymorphs (Al2SiO5): Ab-Initio Modelling
Doklady Earth Sciences ( IF 0.9 ) Pub Date : 2020-04-01 , DOI: 10.1134/s1028334x20040091
D. P. Krylov , A. B. Kuznetsov , A. A. Gavrilova

The β-factor dependences on temperature upon 18O/16O substitution have been originally deduced in andalusite, sillimanite and kyanite accounting for pressure effect: 1000lnβand(18O/16O) = 10.66466x – 0.19330x2 + 0.00282x3 + P(0.12748x – 0.00289x2) 1000lnβsil(18O/16O) = 10.51480x – 0.17485x2 + 0.001406x3 + P(0.12124x – 0.00286x2) 1000lnβky(18O/16O) = 10.14019x – 0.07573x2 + 0.00550x3 + P(0.09907x – 0.00206x2), x = 106/T2 (K)–2, P is pressure (GPa). The relations can be used in isotope geothermometry. Pressure produces an increase of the β-factors and consequently, δ18O\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_{{{\text{A}}{{{\text{l}}}_{{\text{2}}}}{\text{Si}}{{{\text{O}}}_{{\text{5}}}}}}$$\end{document} up to ≈0.5‰ in conditions of the “cold” subduction (at extremely low dT/dP gradients).

中文翻译:

蓝晶石-硅线石-红柱石多晶型物 (Al2SiO5) 中的同位素分馏和压力对 18O/16O 的影响:Ab-Initio 建模

β-因子对 18O/16O 取代的温度依赖性最初是在考虑压力效应的红柱石、硅线石和蓝晶石中推导出来的:1000lnβand(18O/16O) = 10.66466x – 0.19330x2 + 0.00280x1204+P.00280.x1204 )1000lnβsil(18O / 16O)= 10.51480x - 0.17485x2 + 0.001406x3 + P(0.12124x - 0.00286x2)1000lnβky(18O / 16O)= 10.14019x - 0.07573x2 + 0.00550x3 + P(0.09907x - 0.00206x2), x = 106/T2 (K)–2,P 是压力 (GPa)。该关系可用于同位素地球测温。压力会增加 β 因子,因此,
更新日期:2020-04-01
down
wechat
bug