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High-efficiency methanol oxidation electrocatalysts realized by ultrathin PtRuM-O (M = Ni, Fe, Co) nanosheets.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-06-13 , DOI: 10.1039/d0cc00361a
Yue Pan 1 , Hongdong Li 1 , Zuochao Wang 1 , Yi Han 1 , Zhanchao Wu 1 , Xinyi Zhang 1 , Jianping Lai 1 , Lei Wang 1 , Shouhua Feng 1
Affiliation  

A general method for controlling the synthesis of a class of ultrathin PtRuM–O (M = Ni, Fe, Co) NSs is reported for the first time. By optimizing the metal ratio, the Pt7RuNi2–O NS catalyst is found to have the highest electrocatalytic activity (mass activity, 3.57 A mgPt−1) for the MOR among PtRuM–O NSs and PtRu–O NSs, which is 10.5 times higher than that of commercial Pt/C (0.34 A mgPt−1). And the Pt7RuNi2–O NSs also have better stability and CO anti-poisoning properties in the prepared materials. In addition, the ultrathin Pt7RuNi2–O NS catalyst also shows the highest performance among reported Pt-based catalysts for the MOR in acidic medium.

中文翻译:

由超薄 PtRuM-O(M = Ni、Fe、Co)纳米片实现的高效甲醇氧化电催化剂。

首次报道了一种控制合成一类超薄 PtRuM-O (M = Ni, Fe, Co) NSs 的通用方法。通过优化金属比例,发现 Pt 7 RuNi 2 -O NS 催化剂对 PtRuM-O NSs 和 PtRu-O NSs 中的 MOR具有最高的电催化活性(质量活性,3.57 A mg Pt -1),即比商业 Pt/C (0.34 A mg Pt -1 )高 10.5 倍。并且Pt 7 RuNi 2 -O NSs在制备的材料中也具有更好的稳定性和CO抗中毒性能。此外,超薄 Pt 7 RuNi 2-O NS 催化剂在已报道的用于酸性介质中 MOR 的 Pt 基催化剂中也表现出最高的性能。
更新日期:2020-08-06
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