Phosphorothioates, phosphonothioates, phosphinothioates and phosphonodithioates are organophosphorus compounds with widespread application, especially in the fields of agrochemicals, medicinal chemistry and materials chemistry. Herein, we review modern methods for the construction of the phosphorus‐sulfur bonds in these important functional groups. This review is organised on the basis of the different synthetic approaches, with the advantages and disadvantages of each also examined.

中文翻译：

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在有机磷化合物中形成磷硫键的现代合成方法

硫代磷酸酯，硫代磷酸酯，硫代磷酸酯和二硫代磷酸酯是广泛应用的有机磷化合物，特别是在农业化学，药物化学和材料化学领域。本文中，我们回顾了在这些重要官能团中构建磷-硫键的现代方法。这次审查是根据不同的综合方法来组织的，还对每种方法的优缺点进行了检查。