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Investigation of electrical properties of organophosphazene layer based photodiode
Chemical Physics ( IF 2.0 ) Pub Date : 2020-06-13 , DOI: 10.1016/j.chemphys.2020.110897
Kenan Koran , Bilal Arif , Dilawar Ali , Ayşegül Dere , Furkan Özen , Abdullah G. Al-Sehemi , A. Al-Ghamdi , Ahmet Orhan Görgülü , Fahrettin Yakuphanoğlu

New cyclotriphosphazene compound bearing dioxyphenylcoumarin group (DCP-1) was synthesized from the reactions of 7,8-dihydroxy-3-(4-chlorophenyl)coumarin (3) containing chlorine as a side group at para position with cyclotriphosphazene (DCP). The structures of the compounds were determined using 1H, 13C APT, 31P NMR, FT-IR and elemental analysis spectroscopy methods. The organic layer was deposited onto the p-Si substrate to obtain an Al/p-si/phosphazene (DCP-1)/Al diode. The photoresponse and photocapacitance properties of the diode were analyzed under various solar light intensities. The photocurrent and photocapacitance results suggest that the studied device exhibits both photodiode and photocapacitor behavior. The diode indicates a linear photoresponse behavior. The photoswitching behavior of the diode is controlled by solar light intensity. The interface states density of the diode was found to be order of 1012 eV-1cm2. The value of interface states density indicates that the photocapacitor behavior of the diode is significant for photocapacitor applications.



中文翻译:

基于有机磷腈层的光电二极管的电性能研究

新环三磷腈化合物轴承dioxyphenylcoumarin基(DCP-1)从的反应合成7,8-二羟基-3-(4-氯苯基)香豆素含氯作为侧基(3)的对位置与环三磷腈(DCP) 。使用1 H,13 C APT,31 P NMR,FT-IR和元素分析光谱法确定化合物的结构。将有机层沉积在p-Si衬底上以获得Al / p-si /磷腈(DCP-1)/铝二极管。在各种太阳光强度下分析了二极管的光响应和光电容特性。光电流和光电容结果表明,所研究的器件同时具有光电二极管和光电容器的性能。二极管表示线性光响应行为。二极管的光开关行为由太阳光强度控制。发现二极管的界面状态密度为10 12 eV -1 cm 2的量级。界面状态密度的值表明,二极管的光电容器性能对于光电容器应用而言非常重要。

更新日期:2020-06-18
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