Sulfonyl Hydrazides in Organic Synthesis: A Review of Recent Studies,Advanced Synthesis & Catalysis

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Sulfonyl Hydrazides in Organic Synthesis: A Review of Recent Studies
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-06-10 , DOI: 10.1002/adsc.202000466
Shuangte Zhao ₁ , Kaijun Chen ₁ , Ling Zhang ₁ , Weiguang Yang ₂ , Dayun Huang ₁

Affiliation

Sulfonyl hydrazides are widely used as organic reagents. Advances in the past decade are summarized in the following categories by key intermediates: (1) [RO₂S^.]; (2) RO₂SSR; (3) [ArS^.]; (4) [RO₂S⁻]; (5) RSO₂‐[Metal] species; (6) Ar‐[Metal] species; (7) RSX; (8) RS‐DBU; (9) nucleophilic amino group; (10) sulfonyl hydrazides as diazene or sulfinic acid surrogate. Reactions with alkenes, alkynes, aldehydes, alcohols, thiophenol, Grignard reagents, among others, are discussed. We hope this review will promote future research in this area.

中文翻译：

磺酰肼类化合物在有机合成中的研究进展

磺酰肼被广泛用作有机试剂。（1）[RO：在过去十年进展是由关键中间体总结于以下类别₂小号^。]; （2）RO ₂ SSR；（3）[ArS ^。]; （4）[RO ₂小号^- ]; （5）RSO _2- [金属]物种；（6）Ar‐ [金属]物种；（7）RSX；（8）RS‐DBU；（9）亲核氨基；（10）磺酰肼作为重氮或亚磺酸的替代物。讨论了与烯烃，炔烃，醛，醇，硫酚，格氏试剂等的反应。我们希望这篇评论能够促进该领域的未来研究。

更新日期：2020-06-10

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