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Stereospecific synthesis of phosphatidylglycerol using a cyanoethyl phosphoramidite precursor.
Chemistry and Physics of Lipids ( IF 3.4 ) Pub Date : 2020-06-11 , DOI: 10.1016/j.chemphyslip.2020.104933 Zachary J Struzik 1 , Ashley N Weerts 1 , Judith Storch 2 , David H Thompson 1
中文翻译：
使用氰乙基亚磷酰胺前体立体有择合成磷脂酰甘油。
更新日期：2020-06-28
Chemistry and Physics of Lipids ( IF 3.4 ) Pub Date : 2020-06-11 , DOI: 10.1016/j.chemphyslip.2020.104933 Zachary J Struzik 1 , Ashley N Weerts 1 , Judith Storch 2 , David H Thompson 1
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Phosphatidylglycerols (PG) are a family of naturally occurring phospholipids that are responsible for critical operations within cells. PG are characterized by an (R) configuration in the diacyl glycerol backbone and an (S) configuration in the phosphoglycerol head group. Herein, we report a synthetic route to provide control over the PG stereocenters as well as control of the acyl chain identity.
中文翻译：
使用氰乙基亚磷酰胺前体立体有择合成磷脂酰甘油。
磷脂酰甘油 (PG) 是一类天然存在的磷脂，负责细胞内的关键操作。PG 的特征在于二酰基甘油骨架中的 ( R ) 构型和磷酸甘油头基中的 ( S ) 构型。在这里，我们报告了一种合成路线，以提供对 PG 立体中心的控制以及对酰基链身份的控制。
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