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Electrophoretic deposition of antimonene for photoelectrochemical applications
Applied Materials Today ( IF 7.2 ) Pub Date : 2020-06-10 , DOI: 10.1016/j.apmt.2020.100714
Jesús Barrio , Carlos Gibaja , Miguel García-Tecedor , Liel Abisdris , Iñigo Torres , Neeta Karjule , Sixto Giménez , Menny Shalom , Félix Zamora

Antimonene is a recently developed two-dimensional material with outstanding expected physical properties based on theoretical calculations. Liquid phase-exfoliation has become the most straight forward preparation method to produce stable antimonene suspensions. However, the processing and deposition on substrates of antimonene is still required towards its exploitation in various fields, as current challenges in this research area. Despite the high current research interest in antimonene, the fabrication of Sb-films and its utilization in photoelectrochemical devices remains still unexplored. Herein, the electrophoretic deposition of antimonene on different substrates and its activity as absorber and hole acceptor layer in photoelectrochemical cell (PEC) is reported. The obtained results confirm that the photoelectrochemical performance of the antimonene films electrophoretically deposited on titanium dioxide exhibits an enhanced optical absorption and charge separation properties, compared to pristine TiO2 films. Furthermore, electrochemical measurements reveal that the antimonene films act as hole acceptor layers, enabling better PEC performance.



中文翻译:

电泳沉积锑用于光电化学

根据理论计算,锑是一种新近开发的二维材料,具有出色的预期物理性能。液相剥离法已成为制备稳定的锑悬浮液的最直接方法。然而,作为该研究领域中的当前挑战,在各个领域中,仍需要对其进行处理和沉积在其上的锑。尽管目前对锑的研究兴趣很高,但Sb膜的制造及其在光电化学装置中的利用仍未被探索。在本文中,报道了锑在不同基板上的电泳沉积及其在光电化学电池(PEC)中作为吸收层和空穴受体层的活性。2部电影。此外,电化学测量表明,锑膜可充当空穴受体层,从而实现更好的PEC性能。

更新日期:2020-06-10
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