A highly diastereoselective dearomatization of naphthalenes via a Pd-catalyzed 1,4-difunctionalization reaction is described. In the presence of a commercially available palladium precursor and ligand, intramolecular dearomative Heck-type insertion provides π-allylpalladium intermediates which are readily captured by a series of nucleophiles in excellent yields (up to 99%). This reaction features mild conditions, broad substrate scope, and useful transformations of the products.

中文翻译：

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钯催化萘的1,4-双官能化脱芳烃

描述了通过Pd 催化的 1,4-双官能化反应对萘进行高度非对映选择性脱芳构化。在市售的钯前体和配体存在的情况下，分子内脱芳烃 Heck 型插入提供了 π-烯丙基钯中间体，这些中间体很容易被一系列亲核试剂以优异的产率（高达 99%）捕获。该反应具有条件温和、底物范围广、产物转化有用等特点。