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rGO supported self-assembly of 2D nano sheet of (g-C3N4) into rod-like nano structure and its application in sonophotocatalytic degradation of an antibiotic.
Ultrasonics Sonochemistry ( IF 8.4 ) Pub Date : 2020-06-10 , DOI: 10.1016/j.ultsonch.2020.105218
V Vinesh 1 , Muthupandian Ashokkumar 2 , B Neppolian 1
Affiliation  

Graphitic carbon nitride (g-C3N4) is an analog of graphite due to its unique electronic structure. g-C3N4 based materials have been used in photocatalytic applications. However, pure g-C3N4 suffers from major shortcomings which include poor disparity, low surface area and a high recombination rate of photo generated electron-hole pairs that significantly reduce its photocatalytic activity. In this work, self-assembly of g-C3N4 sheet into rod shaped g-C3N4 was developed via a simple polymerisation method. A composite made of g-C3N4 nanorods and rGO (rGO-RCN) was also prepared. The band gap g-C3N4 was shifted from 2.77 to 2.6 eV evidented by UV-DRS data. As a result, rGO-RCN showed a relatively high absorption in the visible region. Moreover, a fast electron transfer rate was observed with rGO-RCN composite as conformed from PL analysis and photocurrent measurement. The formation of nanorod and sheet morphologies was confirmed via TEM analysis. The photocatalytic activities of prepared sheet-g-C3N4 (SCN), Rod g-C3N4 (RCN), reduced graphene oxide supported sheet-g-C3N4 (rGO-SCN) and reduced graphene oxide supported Rod-g-C3N4 (rGO-RCN) were evaluated using a commonly used antibiotic (tetracycline). Among these catalysts, rGO-RCN nanocomposite showed sonophotocatalytic activity 3 times higher compared to pure g-C3N4. This superior sonophotocatalytic activity could be due to enhanced visible light absorption of the material, active sites generated by ultrasound, and the high electron transport property of rGO.



中文翻译:

rGO支持将(g-C3N4)二维纳米片自组装成棒状纳米结构,并支持其在声光催化降解抗生素中的应用。

石墨碳氮化物(gC 3 N 4)由于其独特的电子结构而与石墨类似。基于gC 3 N 4的材料已用于光催化应用。然而,纯gC 3 N 4的主要缺点包括视差差,表面积低以及光生电子-空穴对的高复合率,这大大降低了其光催化活性。在这项工作中,通过简单的聚合方法开发了将gC 3 N 4片材自组装成棒状gC 3 N 4的方法。由gC 3 N 4制成的复合材料还制备了纳米棒和rGO(rGO-RCN)。由UV-DRS数据证实,带隙gC 3 N 4从2.77变化到2.6eV。结果,rGO-RCN在可见光区域显示出较高的吸收。此外,rGO-RCN复合材料的快速电子传输速率与PL分析和光电流测量一致。通过TEM分析证实了纳米棒和薄片形态的形成。制备的片状gC 3 N 4(SCN)棒状gC 3 N 4(RCN),还原性氧化石墨烯负载的片状gC 3 N 4(rGO-SCN)和还原性氧化石墨烯负载的Rod-gC的光催化活性使用常用的抗生素(四环素)评估3 N 4(rGO-RCN)。在这些催化剂中,rGO-RCN纳米复合材料的声光催化活性是纯gC 3 N 4的3倍。这种优越的声光催化活性可能是由于增强了材料的可见光吸收,超声产生的活性位点以及rGO的高电子传输性能。

更新日期:2020-06-23
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