Visible‐Light‐Enabled Multicomponent Cascade Transformation from Indoles to 2‐Azidoindolin‐3‐yl 2‐Aminobenzoates,Advanced Synthesis & Catalysis

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Visible‐Light‐Enabled Multicomponent Cascade Transformation from Indoles to 2‐Azidoindolin‐3‐yl 2‐Aminobenzoates
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-06-08 , DOI: 10.1002/adsc.202000637
Ling‐Ling Zhang ₁ , Meng‐Meng Xu ₁ , Wen‐Bin Cao ₁ , Xiao‐Ping Xu ₁ , Shun‐Jun Ji ₁

Affiliation

The synthesis of 2‐azido‐1‐benzoylindolin‐3‐yl 2‐benzamidobenzoate commencing from (1H‐indol‐1‐yl)(phenyl)methanone and trimethylsilyl azide (TMSN₃) under oxygen atmosphere is described in this paper. This transformation proceeds via a sequential dearomatization and ring‐opening cascade reaction of indoles in a cascade manner.

中文翻译：

可见光使多组分级联从吲哚转变为2-叠氮吲哚-3-基2-氨基苯甲酸酯

本文描述了在氧气气氛下由（1 H-吲哚-1-基）（苯基）甲酮和三甲基甲硅烷基叠氮化物（TMSN ₃）合成2-叠氮基-1-苯甲酰基吲哚-3-基-2-苯甲酰胺基苯甲酸。这种转化通过级联方式依次进行吲哚的脱芳香化和开环级联反应进行。

更新日期：2020-08-04

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