Abstract An adequate understanding of the kinetics of thermal decomposition is fundamental for the design of energy systems. The optimization algorithms have been widely used in the kinetic analysis of thermochemical reactions of biomass materials, for which one of the main concerns is optimization performance. The effect of kinetic parameter values on the n-th order reaction suggests that the optimization performance can be improved based on the kinetic compensation effect (KCE) by considerably narrowing search ranges for kinetic analysis. In this paper, a generalized kinetic method called ETp method is proposed based on KCE and optimization calculation. Analyses verify that the method is generally applicable for a wide variety of reaction mechanisms and kinetic models. The good performance of the method is confirmed by experimental and synthetic data.

中文翻译：

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基于动力学补偿效应和优化计算的动力学分析

摘要 充分理解热分解动力学是能源系统设计的基础。优化算法已广泛应用于生物质材料热化学反应的动力学分析，其中主要关注的问题之一是优化性能。动力学参数值对 n 级反应的影响表明，可以基于动力学补偿效应 (KCE) 通过显着缩小动力学分析的搜索范围来提高优化性能。在本文中，基于KCE和优化计算，提出了一种称为ETp方法的广义动力学方法。分析证实该方法普遍适用于各种反应机制和动力学模型。