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A 500 Wh/kg Lithium-Metal Cell Based on Anionic Redox
Joule ( IF 38.6 ) Pub Date : 2020-06-09 , DOI: 10.1016/j.joule.2020.05.012
Yu Qiao , Han Deng , Ping He , Haoshen Zhou

Benefiting from the high-energy-density Li2O-based cathode and ultra-stable ether-based electrolyte system, we report a low-cost and high-energy-density 500 Wh/kg-cell Li-metal pouch cell driven by pure anionic redox activity. The non-superoxo/O2 “safe” charge depth has been extended to 750 mAh/g∼Li2O. Fairly taking the entire cathode mass loading (including inactive components) into calculation, a specific capacity of 477.3 mAh/g can be achieved. The cost/price of cathode catalytic matrix has been efficiently controlled by the employment of low-cost Ni-based catalyst substrate. Benefitting from the electrolyte modification, highly efficient and long-term stable Li-metal cycling guarantees the employment of limited Li metal in full-cell systems, which largely boosts the pouch-cell-level energy density. Finally, by explicitly sharing and analyzing the promoting space of each cell-level parameter in the current pouch-cell system, we want to pass a straightforward message to battery researchers, directing their attention to the development of this promising low-cost and high-energy-density cell system.



中文翻译:

基于阴离子氧化还原的500 Wh / kg锂金属电池

从高能量密度的锂受益2 O系阴极和超稳定醚系电解质系统中,我们报道了一种低成本,高能量密度的500瓦时/千克-cell锂金属袋状电池单元由纯驱动阴离子氧化还原活性。非superoxo / O 2 “安全”充电深度已扩展至750 mAh / g〜Li 2O.合理地计算整个阴极质量负荷(包括惰性成分),可以实现477.3 mAh / g的比容量。阴极催化剂基质的成本/价格已通过采用低成本的镍基催化剂基质得到有效控制。得益于电解液的改性,高效且长期稳定的锂金属循环可确保在全电池系统中使用有限的锂金属,从而极大地提高了袋式电池级的能量密度。最后,通过明确共享和分析当前袋式电池系统中每个电池级参数的促进空间,我们希望向电池研究人员传递直接的信息,将他们的注意力集中在这种有前途的低成本和高成本的电池上。能量密度电池系统。

更新日期:2020-06-09
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