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Alkyl perchlorates in the Ritter-type reaction. Synthesis of N-alkylamides
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-05-01 , DOI: 10.1007/s11172-020-2858-8
N. V. Yashin , P. O. Markov , K. N. Sedenkova , D. A. Vasilenko , Yu. K. Grishin , T. S. Kuznetsova , E. B. Averina

The Ritter-type reaction of alkyl perchlorates with nitriles of various structures was systematically studied. The reaction has a wide scope and proceeds under extremely mild conditions without any catalysts or special activation of reagents. A structural diversity of the obtained by the Ritter-type reaction N-alkyl amides bearing small ring, double bonds, additional functional groups, aromatic and adamantane fragments, was demonstrated.

中文翻译:

Ritter 型反应中的高氯酸烷基酯。N-烷基酰胺的合成

系统地研究了高氯酸烷基酯与各种结构腈的Ritter型反应。该反应范围广,在极其温和的条件下进行,无需任何催化剂或特殊活化试剂。证明了通过 Ritter 型反应获得的 N-烷基酰胺具有小环、双键、附加官能团、芳香族和金刚烷片段的结构多样性。
更新日期:2020-05-01
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