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The effect of the triethanolamine: glycerol deep eutectic solvent on the yield, fatty acid composition, antioxidant activity, and physicochemical properties of black mustard ( Brassica nigra L.) seed oil
Journal of Food Measurement and Characterization ( IF 2.9 ) Pub Date : 2020-06-09 , DOI: 10.1007/s11694-020-00503-3
Biljana S. Đorđević , Dragan Z. Troter , Zoran B. Todorović , Ivica G. Đalović , Ljiljana P. Stanojević , Petar M. Mitrović , Vlada B. Veljković

This study reports the yields, physicochemical properties, fatty acid compositions, and antioxidant activities of black mustard (Brassica nigra L.) seed oils extracted by cold pressing and the solvent extraction using different solvents (n–hexane, trichloroethylene, and a mixture of trichloroethylene and the triethanolamine:glycerol deep eutectic solvent (TEOA:G DES) with no or after pretreatment with the TEOA:G DES. Density (0.9791 ± 0.0003–0.9851 ± 0.0003 g/cm3), viscosity (121.15 ± 1.62–123.32 ± 0.10 mPa⋅s), boiling point (179–185 ± 1 °C), refractive index (1.4692 ± 0.0006–1.4758 ± 0.0011), acid (2.08 ± 0.19–3.22 ± 0.15 mg KOH/g), iodine (99.2 ± 1.6–105.4 ± 1.5 g I2/100 g), peroxide (1.68 ± 0.01–1.82 ± 0.03 mmol O2/kg), and saponification values (165.1 ± 2.7–169.4 ± 2.3 mg KOH/g), fatty acid composition and antioxidant activity of the extracted oil were determined in order to evaluate its potential use as a foodstuff, a pharmaceutical or a feedstock for biodiesel production. Although the maceration of black mustard seeds with sole trichloroethylene yielded the highest oil yield of 31.10 ± 0.42 g/100 g, it required almost twice the volume of trichloroethylene compared to the volume applied in the macerations after the pre–treatment with the TEOA:G DES and with the mixture of trichloroethylene/TEOA:G DES. The oil extracted by the extraction in the presence of TEOA:G DES has similar physicochemical properties but better antioxidant activity than the oil extracted by cold pressing.

中文翻译:

三乙醇胺:甘油深层共晶溶剂对黑芥菜籽油的产量,脂肪酸组成,抗氧化活性和理化性质的影响

这项研究报告的产率,理化性质,脂肪酸的组合物,和黑芥末的抗氧化活性(黑芥L.)种子油通过冷压和使用不同溶剂的溶剂提取(萃取Ñ正己烷,三氯乙烯,三氯乙烯和的混合物或不使用TEOA:G DES预处理的三乙醇胺:甘油深共熔溶剂(TEOA:G DES),密度(0.9791±0.0003–0.9851±0.0003 g / cm 3),粘度(121.15±1.62–123.32±0.10) mPa·s),沸点(179–185±1°C),折射率(1.4692±0.0006–1.4758±0.0011),酸(2.08±0.19–3.22±0.15 mg KOH / g),碘(99.2±1.6– 105.4±1.5克每升2 / 100g的),过氧化(1.68±0.01-1.82±0.03毫摩尔Ò 2/ kg),并测定皂化值(165.1±2.7–169.4±2.3 mg KOH / g),脂肪酸组成和提取油的抗氧化活性,以评估其作为食品,药品或原料的潜在用途生物柴油生产。尽管将黑芥末种子与唯一的三氯乙烯浸渍后产生的最高油产量为31.10±0.42 g / 100 g,但与用TEOA:G预处理后在浸渍液中施加的体积相比,其所需三氯乙烯的体积几乎是其两倍。 DES,以及三氯乙烯/ TEOA:G DES的混合物。在TEOA:G DES存在下,通过萃取提取的油具有比通过冷压萃取的油相似的理化性质,但具有更好的抗氧化活性。
更新日期:2020-06-09
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