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Vesicle-Templated Polymerization, a Review.
Biomacromolecules ( IF 5.5 ) Pub Date : 2020-06-08 , DOI: 10.1021/acs.biomac.0c00558
Alexander M van Herk 1
Affiliation  

Vesicle-templated polymerization has developed into a mature research area over the last 35 years. The main purpose of this approach was to produce hollow polymeric nanocapsules from low-cost chemicals, utilizing a simple emulsion-polymerization-like process. Over the years, understanding of the different varieties of the approach has grown. In retrospect, the characterization methods utilized to determine the morphologies are essential to draw the right conclusions. In this Review, first, an overview of the earlier attempts to produce nanocapsules with uniformous wall thickness will be given, looking at the results with the current understandings, greatly enhanced by quantification of the different morphologies through cryo-TEM images. The latest approach, reactive oligomer assisted transcriptive synthesis, seems to be able to fulfill the initial purpose and almost 100% of nanocapsule morphologies can be formed under the right conditions.

中文翻译:

囊泡模板聚合,评论。

在过去的35年中,囊泡模板聚合已发展成为一个成熟的研究领域。这种方法的主要目的是利用一种类似于乳液聚合的简单工艺,用低成本的化学药品生产中空的聚合物纳米胶囊。多年以来,人们对这种方法的不同种类的了解不断增长。回顾过去,用于确定形态的表征方法对于得出正确的结论至关重要。在本综述中,首先,将给出对制备壁厚均匀的纳米胶囊的较早尝试的概述,结合当前的理解,结合通过冷冻TEM图像对不同形态进行定量分析,结果将大大增强。最新的方法是反应性低聚物辅助转录合成,
更新日期:2020-06-08
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