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Nanocasted polytriazine-SBA-16 mesoporous composite for the conversion of CO2 to cyclic carbonates
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2020-06-07 , DOI: 10.1016/j.jcou.2020.101189
Ankushi Bansal , Ruchi Sharma , Paritosh Mohanty

A hierarchical nanoporous composite of polytriazine-SBA-16 (PT@SBA-16) was synthesized by an infiltration followed by condensation method using rapid microwave assisted approach. The specific surface area, SABET of 351 m2 g−1 was estimated in the PT@SBA-16 with a pore volume of 0.433 cm3 g−1. The PSD is shifted towards a small pore regime which centered ∼3 and 5.3 nm in comparison to 5.7 nm in the parent SBA-16. Almost 46 wt% of the PT was loaded in the SBA-16 while keeping its SABET still in the modest range. The PT@SBA-16 as a multifunctional (hydroxyl and amine) heterogeneous catalyst was utilized for the conversion of CO2 to cyclic carbonates with 100% conversion and selectivity at mild experimental condition. Retention of 80% of its initial catalytic activity even after five consecutive cycles, easily recyclable, co-catalyst and solvent-free conditions made this an efficient catalyst for the conversion of CO2 to molecules of industrial importance.



中文翻译:

纳米铸造的聚三嗪-SBA-16介孔复合材料,用于将CO 2转化为环状碳酸酯

通过快速微波辅助渗透法,缩聚法合成了聚三嗪-SBA-16(PT @ SBA-16)的纳米级多孔复合材料。在PT @ SBA-16中估算的比表面积SA BET为351 m 2 g -1,孔体积为0.433 cm 3  g -1。PSD朝着一个小孔区域移动,与母体SBA-16中的5.7 nm相比,中心位于〜3和5.3 nm。几乎46 wt%的PT被装载到SBA-16中,同时保持其SA BET仍在适中的范围内。PT @ SBA-16作为多功能(羟基和胺)非均相催化剂用于转化CO 2在温和的实验条件下可以100%的转化率和选择性地合成环状碳酸酯。即使在连续五个循环后仍保持80%的初始催化活性,易于回收,助催化剂和无溶剂条件,这使其成为将CO 2转化为具有工业重要性的分子的有效催化剂。

更新日期:2020-06-07
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