Graphene with excellent comprehensive properties has been considered as a promising filler to reinforce ceramics. While numerous studies have been devoted to the improvement of mechanical and electrical properties, incorporating graphene to ceramics also offers new opportunities for endowing ceramics with versatility. In this review, the recent development of graphene/ceramic bulk composites is summarized with the focus on the construction of well-designed architecture and the realization of multifunctional applications. The processing technologies of the composites are systematically summarized towards homogeneous dispersion and even ordered orientation of graphene sheets in the ceramic matrix. The improvement of composites in mechanical, electrical, electromagnetic, and thermal performances is discussed. The novel multifunctional applications brought by smart integration of graphene in ceramics are also addressed, including microwave absorption, electromagnetic interference shielding, ballistic armors, self-monitor damage sensors, and energy storage and conversion.

中文翻译：

---

石墨烯/陶瓷复合材料的可控制备及其多功能应用

具有优异综合性能的石墨烯被认为是增强陶瓷的有前途的填料。尽管已经进行了许多研究来改善机械和电气性能，但是将石墨烯掺入陶瓷中也为赋予陶瓷多功能性提供了新的机会。在这篇综述中，总结了石墨烯/陶瓷本体复合材料的最新发展，重点是精心设计的架构的构建和多功能应用程序的实现。系统地总结了复合材料的加工技术，以使石墨烯片在陶瓷基体中均匀分散，甚至有序取向。讨论了复合材料在机械，电气，电磁和热性能方面的改进。