Waste to MOFs: sustainable linker, metal, and solvent sources for value-added MOF synthesis and applications,Green Chemistry

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Waste to MOFs: sustainable linker, metal, and solvent sources for value-added MOF synthesis and applications
Green Chemistry ( IF 9.3 ) Pub Date : 2020-06-05 , DOI: 10.1039/d0gc00353k
El-Sayed M. El-Sayed _{1,

2,

3,

4,

5} , Daqiang Yuan _{1,

2,

3,

4,

5}

Affiliation

Greening of the synthetic route for metal–organic frameworks (MOFs) has attracted much interest as a decisive step for practical industrial applications. For a more feasible process, employing waste plastic materials as a potential linker source for MOF synthesis is highly encouraging, combining a sustainable and environmentally friendly approach for scale-up production. The process is more economical when the whole MOF synthesis can be achieved based on waste metal and linker sources in the presence of green solvents derived from waste materials as well. Herein, we present a waste valorization approach for the preparation of MOFs based on different recycled polymer waste materials, MOFs based on waste metal sources, and MOFs based on the coupling of waste sources for both the organic ligand and metal center. This approach not only recycles discarded products but also produces high value-added costly materials for different applications.

中文翻译：

转移至MOF的废物：用于增值MOF合成和应用的可持续连接剂，金属和溶剂来源

金属-有机骨架（MOFs）合成路线的绿色环保作为实际工业应用中的决定性步骤已引起了广泛的关注。对于更可行的过程，将废塑料用作MOF合成的潜在连接物来源是非常令人鼓舞的，将可持续和环境友好的方法相结合用于大规模生产。当在废料衍生的绿色溶剂的存在下，也可以基于废金属和接头来源完成整个MOF合成时，该方法将更为经济。在这里，我们提出了一种基于不同回收聚合物废料的MOF，基于废金属源的MOF，以及基于有机配体和金属中心的基于废源耦合的MOF的废物估价方法。

更新日期：2020-07-06

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