Piano-Stool Iron Complexes as Precatalysts for gem-Specific Dimerization of Terminal Alkynes,Organometallics

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Piano-Stool Iron Complexes as Precatalysts for gem-Specific Dimerization of Terminal Alkynes
Organometallics ( IF 2.5 ) Pub Date : 2020-06-04 , DOI: 10.1021/acs.organomet.0c00271
Qiuming Liang ₁ , Kasumi Hayashi ₁ , Karolina Rabeda ₁ , Jose L. Jimenez-Santiago ₁ , Datong Song ₁

Affiliation

A series of piano-stool Fe–NHC complexes have been prepared and characterized. The NHC ligands used herein possess a benzyl and a mesityl wingtip groups and have different electronic structures within the NHC rings. The catalytic activities of these Fe complexes have been examined for the homodimerization of terminal alkynes.

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